Smith Michael B. March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure

7th edition. — Wiley, 2013. — 6119 p. — ISBN 9781118472217.The new, revised and updated 7th edition of March’s Advanced Organic Chemistry clearly explains the theories and examples of organic chemistry, providing the most comprehensive resource about organic chemistry available. Readers are guided on planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions.The first five chapters deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Chapters 6 to 9 are concerned with general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation, and finally the relationship between structure and reactivity.The last 10 chapters cover the nature and the scope of organic reactions and their mechanisms.Localized Chemical Bonding
Delocalized Chemical Bonding
Bonding Weaker Than Covalent
Stereochemistry and Conformation
Carbocations, Carbanions, Free Radicals, Carbenes, and Nitrenes
Mechanisms and Methods of Determining Them
Irradiation Processes in Organic Chemistry
Acids and Bases
Effects of Structure and Medium on Reactivity
Aliphatic Substitution, Nucleophilic and Organometallic
Aromatic Substitution, Electrophilic
Aliphatic, Alkenyl, and Alkynyl Substitution, Electrophilic and Organometallic
Aromatic Substitution: Nucleophilic and Organometallic
Substitution Reactions: Radical
Addition to Carbon–Carbon Multiple Bonds
Addition to Carbon–Hetero Multiple Bonds
Eliminations
Rearrangements
Oxidations and Reductions