Reisman A. Phase Equilibria. Basic Principles, Applications, Experimental Techniques

Academic Press, 1970. — 541 p. — (Physical Chemistry, vol.19). — ISBN: 9781483265841.Phase Equilibria: Basic Principles, Applications, Experimental Techniques presents an analytical treatment in the study of the theories and principles of phase equilibria.
The book is organized to afford a deep and thorough understanding of such subjects as the method of species model systems; condensed phase-vapor phase equilibria and vapor transport reactions; zone refining techniques; and nonstoichiometry.
Physicists, physical chemists, engineers, and materials scientists will find the book a good reference material.Some Preliminary Remarks and Observations
Thermodynamics and the Phase Rule
Definition of Terms and Concepts
The Thermodynamic Basis of the Phase Rule
Systems of One Component—Temperature Effects
Systems of One Component—Pressure Effects and the Continuous Nature of Metastability
Complex Metastability in One-Component Systems
Other Aspects of One-Component Behavior
Enthalpy and Entropy Diagrams of State for Unary Systems
Multicomponent Systems, Homogeneous Systems, and the Equilibrium Constant
Multicomponent Systems, the Equilibrium Constant, and Heterogeneous Systems
The Thermodynamic Parameters-Fugacity and Activity
Two-Component Systems-Systems in Which One Phase Is Pure and in Which Species and Component Mole Terms Are Equivalent-Simple Eutectic Interactions
Graphical Representations of Simple Eutectic Interactions
Eutectic Systems Continued—The Parameter ΔHfusion/Tmelting and Its Influence on the Contour of Eutectic Liquidus Curves
Eutectic Interactions Continued—The Effects of Homogeneous Equilibria on Liquidus Contours
Common Species Effects in Simple Eutectic Systems
Eutectic Interactions Continued—The Effects of Association on Liquidus Contours
Eutectic Interactions Continued—Effects of End Member Species Interactions on Liquidus Contours
Eutectic Interactions Continued—Effects of Complete Dissociation on Liquidus Contours
Eutectic Interactions Continued—Graphical Description of the Results of Chapters 16-20
Eutectic Interactions Continued—Single Compound Formation in Binary Systems and Coordinate Transformations
Eutectic Interactions Continued—Multiple Compound Formation in Binary Systems and Coordinate Transformations in Multiple Compound Systems
Eutectic Interactions Continued—p-T-Mx Representations and Phase Changes
Eutectic Interactions Continued—Intermediate Compound Instability—Incongruently Melting Compounds
Liquid Immiscibility in Eutectic Systems
Systems Exhibiting Solid Solubility—Ascending Solid Solutions
Solid Solutions Continued—Graphical Representation of Idealized Systems and Some Comment on Real Systems
Solid Solutions Continued—Complete Liquid Phase Dissociation and Minimum Type Solid Solutions
Hypothetical Examples Using the Equations of Chapter 29
Condensed-Vapor Phase Binary Diagrams
Condensed-Vapor Phase Binary Diagrams Continued—Incongruently Vaporizing Systems
Limited Solid Solubility
Three-Component Systems
Three-Component Solid-Vapor Equilibria—Chemical Vapor Transport Reactions
Experimental Techniques
Appendix: References and Additional Remarks for Chapters 1-36
General Bibliography